Rye
Rye, like the alcohol, can be a bit spicier grain to use. It is often used in combination with other grains, such as 90% corn, 10% rye.
True rye however is made from at least 51% rye grain, most often even more. Nothing says you can't use 100% rye too, although some of that should be in the form of malt, to ensure proper enzymes to convert starch to sugar.
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When you buy rye, be sure it is untreated. As with other grain, seed grain is often treated. Buy untreated rye, cracked or rolled rye.